ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
SYNTHESIS AND PROPERTIES OF 2-SUBSTITUTED 1,4-ENYNE CHLOROHYDRINS
A.M.Garamanov, M.Sh.Gurbanov, A.F.Guliyeva, S.N.Allakhverdiyeva

 

By interaction of 2-substituted 1,4-enyne alcohols with 1-chloro-2,3-epoxy propane in the presence of boron trifluoride etherate there have been synthesized 2-substituted 1,4-enyne chlorohydrin by dehydrochlorination of which epoxy-1,4-enynes and epoxy-1,3,4-triens have been prepared. The addition reaction of the methyl diethyl silane to epoxy-1,4-enynes leads to the formation of mixture of silicoorganic epoxy-1,4-dienes.

 

Keywords : 5-methyl hexen-5-yn-2-ol-1, 2,6-dimethyl hepten-6-in-3-ol-2, 1-chloro-2,3-epoxy propane, boron trifluoride etherate, dehydrochlorination, epoxy-1,4-enyne, epoxy-1,3,4-trien, hydrosilylation
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SUBMITION
THE LAST NUMBER OF THE JOURNAL
№3 2017
CONTENT
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