SELECTIVE COHERENT-SYNCHRONIZED OXIDATION OF ETHYLENE BY HYDROGEN PEROXIDE ON THE per-FTPhPFe3+OH/Al2O3 BIOMIMETIC CATALYST

U.V.Mammadova, I.T.Nagieva, L.M.Gasanova, T.M.Nagiev

The selective gas-phase monooxidation of ethylene by hydrogen peroxide on a biomimetic heterogeneous catalyst (per-FTPhPFe³⁺OH/Al₂O₃) was studied under comparatively mild conditions. A kinetic model that fits the experimental data is studied by different methods on the basis of the most probable mechanism of ethylene oxidation by hydrogen peroxide over a biomimetic catalyst, per-FTPhPFe³⁺OH/Al₂O₃. The comparative analysis of the found kinetic parameters is given.

Keywords : ethylene, oxidation, hydrogen peroxide, biomimetic catalyst, coherency, determinant equation, kinetic model

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№1 2024

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