ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
SYNTHESIS OF AMINOALCOHOLS BASED ON OXYHALOGENATION PRODUCTS OF ALKYLCYCLOHEXENES AND C3, C4 ALIPHATIC AMINES
O.A.Sadygov, Kh.M.Alimardanov, Sh.I.Ismayilova

 

Synthesis of aminocyclohexanols through the steps of hydroxychlor(brom)ination of alkyl- and alkenylcyclohexenes has been proposed in the system: cycloolefin + oxidant + Hhal. It was demonstrated that the oxidation process is induced by the electrophilic intermediates HOX, (X=Cl, Br), which in the "in situ" mode, are added to the multiple bond of substrates by the formation of the corresponding hydroxyhalides. Substitution of halogen atoms for amino groups with the participation of potassium hydroxide leads to the corresponding amino alcohols

Keywords : aminocyclohexanols, synthesis, alkyl- and alkenylhydroxychloro- (bromo)cyclohexanol
View article
SUBMITION
THE LAST NUMBER OF THE JOURNAL
№3 2018
CONTENT
- INFLUENCE OF VARIOUS FACTORS ON THE COMPOSITION OF ELECTRODEPOSITED THIN FILMS Mo–SV.A.Majidzade, S.F.Cafarova, A.Sh.Aliyev, D.B.Tagiyev
- A STUDY OF THE KINETICS AND MECHANISM OF THE SELECTIVE OXIDATIVE DEHYDROGENATION REACTİON OF CYCLOPENTANE TO CYCLOPENTADIENE-1,3 OVER MODIFIED ZEOLITE CATALYSTSA.M.Aliyev, M.Y.Abbasov, Z.A.Shabanova, G.A.Ali-zadeh, M.F.Bahmanov, U.M.Najaf-Guliyev, T.I.HuseynovaMore