ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
STUDY OF THE ARYLATION REACTION OF ETHYLENE BY TOLUENE
A.M.Aliyev, G.A.Ali-zadeh, M.G.Aliyeva, S.R.Mamedova, R.Yu.Agayeva

 The arylation reaction of ethylene by toluene has been studied in the liquid phase with the using of the homogeneous catalytic system Pd(OAc)2+Cu(OAc)2+PPh3, in the semibatch flask reactor under atmospheric pressure. Optimum conditions for the reactions were as follows: mole ratio of the components of the catalytic system Pd(OAs)2:Cu(OAc)2:PPh3=1:2:0.03, concentration of the active mass of the catalytic system, [Pd(OAc)2]=6·10-2÷10-3 mol/l, temperature (95÷105)0C. In these conditions the yield of vinyltoluene is (5÷8) wt.%. It has been proposed as a posible mechanism for the reaction including the formation of the intermediate complexes of palladium acetate with toluene, ethylene and triphenyl phosphine

https://doi.org/10.32737/0005-2531-2019-2-6-10

Keywords : arylation, ethylene, toluene, vinyltoluene, palladium acetate, triphenyl phosphine
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SUBMITION
THE LAST NUMBER OF THE JOURNAL
№2 2019
CONTENT
- STUDY OF THE ARYLATION REACTION OF ETHYLENE BY TOLUENEA.M.Aliyev, G.A.Ali-zadeh, M.G.Aliyeva, S.R.Mamedova, R.Yu.Agayeva
- EFFECT OF ORGANIC MATTER ON HEXAVALENT CHROMIUM REDUCTION BY NANO ZERO VALENT IRON IN SOILG.R.AllahverdiyevaMore