ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
IONIC LIQUIDS AS EXTRAGENTS OF COMPOUNDS NEGATIVELY AFFECTING THE ENVIRONMENTAL PROPERTIES OF DIESEL FUEL
M.J.Ibragimova, S.A.Seidova, S.G.Alieva, H.J.Huseynov, Kh.A.Abdullaeva, F.Yu.Yusifzade

The results of scientific research in the field of liquid-liquid extraction purification of diesel distillates differing in the content of undesirable aromatic and sulfur compounds using various ionic liquids as a selective, environmentally friendly solvent are presented. Different extracting ability of ionic liquids (dipropylammonium, dibutylammonium and N-methylpyrrolidinium acetate, morpholinium formate) in relation to the extracted components of diesel distillate is shown.  In particular, a high degree of purification of the hydrotreated diesel fraction was established when using N-methylpyrrolidinium acetate ionic liquid in the extraction process. The influence of the staged process of extraction purification of mixed diesel distillate based on straight-run diesel fraction (70% vol.) and secondary oil processing products - light gas oil coking and light gas oil catalytic cracking (30% vol.) on the degree of dearomatization and desulfurization of the fuel has been determined. A relatively high yield and degree of purification of diesel fuel were revealed when carrying out the process of extraction purification of the mixed diesel distillate with N-methylpyrrolidinium acetate ionic liquid in three stages. The extraction purification process was studied using IR and UV spectral analysis methods and the possibility of purifying three- and fourcyclic aromatic hydrocarbons from the mixture of straight-run diesel fraction and secondary petroleum products was established when carrying out the extraction process with N-methylpyrrolidinium acetate ionic liquid.

doi.org/10.32737/0005-2531-2024-3-20-28

Keywords : ionic liquid, diesel distillate, extraction purification, raffinate, aromatic hydrocarbons, sulfur compounds
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- IONIC LIQUIDS AS EXTRAGENTS OF COMPOUNDS NEGATIVELY AFFECTING THE ENVIRONMENTAL PROPERTIES OF DIESEL FUELM.J.Ibragimova, S.A.Seidova, S.G.Alieva, H.J.Huseynov, Kh.A.Abdullaeva, F.Yu.YusifzadeMore