The synthesis of N-alkyl- and N-arylaminoimides of endo-, exo-1,2,3,4,11,11-hexachlortri­cyclo[6.2.1.0^5.10]­undec-2-ene-7,8- and endo-1,4,5,6,7,7-hexachlorbicyclo[2.2.1]hex-5-en-2,3-dicarboxylic acids by diene condensation of N-alkyl- and N-arylaminoimides of cis-4-cyclohexene-1,2-dicarboxylic or maleic acids with hexa­chlor­cyclopentadiene has been described. The spatial structure of the prepared aminoimides with opposite synthesis – arylation of the corresponding diamine with anhydrides of above-states acids has been established