N-MONOCHLORAMIDES SULFOACIDS IN SYNTHESIS OF 1-CHLORINE-2-HYDROXY-, -ALKOXY- OR -KARBOXYLALKILES AND THERE DERIVATIVES
The methods of synthesis of 1-chlorine-2-hydroxy-alkoxy or carboxy alkiles synthesis by using key reagents – N-monochloramides of sulfoacids have been worked out. It was found out that octane-1, dodesen-1 and alkyl chloride with chloramines in aprotonic dissolvent in acid environment are sulfamidized by obtaining N-β-chloralkylsulfamides, in protonic solvent forming 1-chloro-2-hydroxy- or alkosyalkiles, and in the presence of acetic acid generated – 1-chlor-2-carboxymethylalkiles. By the substitution of chlorine in obtained compounds with caprylic acid in the presence of 3-ethylamine there have been obtained ether oils with positive characteristics
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