ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
LIQUID-PHASE OXIDATION OF CUMENE BY MOLECULAR OXYGEN IN THE PRESENCE OF N-(p-ACETAMIDPHENYL)IMIDE DICHLOROMALEIC ACID
Ya.M.Nagiyev, E.B.Zeynalov, G.Sh.Asadzade

 

Oxidation reaction of cumene with molecular oxygen at 1000С in the presence of N-(p-acetamidphenyl) imide dichloromaleic acid synthesized has been investigated in vitro by the method developed by us. It is found that imide indicated is an active oxidation catalyst, leading to 70% conversion of hydrocarbon and intensive disintegration of  hydroperoxide to form phenol, аcetophenone, 2-phenyl-2 propanol, 4-methyl-benzoic acid and tert-butybenzene.  N-(p-acet­amid­phenyl)­mide dichloro­maleic acid can be recommended as an active catalyst of synthesis of secondary products of aerobic oxidation alkylbenzenes.

 

Keywords : cumene, aerobic oxidation, N-(p-acetamidphenyl imide dichloromaleic acid, catalytic activity, acetophenone, 2-phenyl-2 propanol, phenol, 4-methyl-benzoic acid, tert-butybenzene
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SUBMITION
THE LAST NUMBER OF THE JOURNAL
№4 2023
CONTENT
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