SELECTIVE COHERENT-SYNCHRONIZED OXIDATION OF ETHYLENE BY HYDROGEN PEROXIDE ON THE per-FTPhPFe3+OH/Al2O3 BIOMIMETIC CATALYST

U.V.Mammadova, I.T.Nagieva, L.M.Gasanova, T.M.Nagiev

The selective gas-phase monooxidation of ethylene by hydrogen peroxide on a biomimetic heterogeneous catalyst (per-FTPhPFe³⁺OH/Al₂O₃) was studied under comparatively mild conditions. A kinetic model that fits the experimental data is studied by different methods on the basis of the most probable mechanism of ethylene oxidation by hydrogen peroxide over a biomimetic catalyst, per-FTPhPFe³⁺OH/Al₂O₃. The comparative analysis of the found kinetic parameters is given.

Keywords : ethylene, oxidation, hydrogen peroxide, biomimetic catalyst, coherency, determinant equation, kinetic model

View article

SUBMITION

THE LAST NUMBER OF THE JOURNAL

№3 2023

CONTENT

- SURFACES OF CRYSTALLIZATION AND PHASE RELATIONS IN THE 6Ag2Se+Ag8SiTe6«6Ag2Te+Ag8SiSe6 RECIPROCAL SYSTEMA.J.Amiraslanova, K.N.Babanly, S.Z.Imamaliyeva, E.I.Akhmedov, Yu.A.Yusibov, M.B.Babanly

- ACID-BASE PROPERTIES OF PHOSPHORYLATED CRUMB RUBBERN.A.Efendiyeva, I.A.Buniyat-zadeh, N.M.Binnetova, N.M.Guliyeva, J.A.Naghiyev, R.M.AlosmanovMore