PHOTOELECTROCHEMICAL SYNTHESIS AND MOLECULAR-WEIGHT DISTRIBUTION OF OLIGO-p-XYLENESULFANIDE
The photoelectrochemical oxidative polycondensation reaction of p-xylenesulfamide by the method of electrolysis in aqueous solution of sulphuric acids has been investigated. The results of exclusion-chromatographic analyses permitted to establish conditions allowing, in contrast to EC method, to carry out oligomerization in mild conditions, to prepare oligomers with high yield and regulated with parameters of molecular-weight distribution.
Keywords : photoelectrochemistry, oxidative polycondensation, illumination, exclusionliquid chromatography, molecular-weight distribution, oligo-p-xylenesulfamide
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