ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
CATALYTIC HYDROSILYLATION OF 1-(HEXEN-5-YN-2-YLOXY)-3-CHLORPROPANOL-2
A.M.Garamanov, D.G.Abdullayev, M.Sh.Gurbanov

 

The addition reaction of trialkylsilanes to 1-(hexen-5-yn-2-yloxy)-3-chlorpropanol-2 in the presence of H2PtCl6.6H2O and (acac)Rh(CO)2 at equimolar ratio of the reacting components has been studied. It has been shown that trialkylsilanes are added to the investigated enyne selectively on triple bond but in two directions with predominance of β-product (relatively oxygen atom).

 

Keywords : hydrosilylation, trialkilsilanes, 1-(hexen-5-yn-2-yloxy)-3-chlorpropanol-2, chloro-platinic acid, acetylacetonatdicarbonyl rhodium, β-, γ-products
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SUBMITION
THE LAST NUMBER OF THE JOURNAL
№3 2020
CONTENT
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