By thermal decomposition penta-kis of tetrahydrofuranate solvated vanadyl complex with (С₅Н₅)₂V=О·(ТНF)₅ (1), produced by hydrolysis of  bis-cyclopentadienyl of vanadium(III) chloride (С₅Н₅)₂VCl (2) under weak basicity vanadium oxide nanostructured thin films on the surface of metal oxide carrier were produced. It was detected that vanadium oxide thin films with thickness of 45 nm were produced at concentration 0.1 mol/100 ml solvent (ТНF) with capacity of 50 ml of spheric Al₂O₃ with 5–7µm carrier.