Conditions have been studied for the formation of complexes of copper with hydroxyhlogenated thiophenol (HHTPh) and aminophenols (APh) (рН_оp 3.0–6.0; λ_маx = 450–460 nm; Δλ = 275– 285 nm; ε_маx = (3.5–4.3) 10⁴; lg K_eq=8.32–9.37). The single time extraction is 98.1–98.6%. The formation of a ligand complex of the composition Cu(II): HHTPh:АPh = 1:2:2 in case of АPh₁ and 1:2:1for АPh₂ was detected. Beer`s law is obeyed within 0.2–16 mkg of copper in 1 ml of the extract. The limit of detection for Cu(II) at P=0.95 makes up  0.010–0.014 mkg/ml, S_r is 0.15–0.045