ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
COMPOSITION AND STRUCTURE OF TRIPLE COPOLYMERS OF N-ALLYLMALEIMIDE, trans-STILBENE AND MALEIC ANHYDRIDE
L.V.Medyakova, S.A.Rzaeva

 

The radically initiated copolymerization of three-component system with participation of bifunctional monomer – N-allylmaleimide, trans-stilbene and maleic anhydride has been carried out. The discrepancy of real compositions of triple copolymers with free-monomer chain growth calculated on model has been established. This fact has been interpreted from position of formation of intermolecular p–p-complexes participating in elementary chain growth reactions. It is shown that the macromolecules of the synthesized triple copolymers consist of dyad complexomers at their various content in macrochain.

 

Keywords : N-allylmaleimide, trans-stilbene, maleic anhydride, radical copolymerization, donor-acceptor complexes, ternary copolymers, composition, structure, unsaturatity
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