COHERENT-SYNCHRONIZED DEHYDROGENATION OF PIPERYDINE TO PYRIDINE BY HYDROGEN PEROXIDE
The coherent-synchronized reactions of decomposition of hydrogen peroxide and dehydrogenation of piperidine have been investigated. The determinant values for each of experiment have been determined. The quantitative estimation of inductive effect of primary reaction (decomposition of hydrogen peroxide) to secondary basic reaction (dehydrogenation of piperidine) has been given. The probable mechanism of coherent-synchronized interaction of decomposition of hydrogen peroxide and dehydrogenation of piperidine by free-radical chain mechanism, where -radical plays the key role in oxidation of substrate has been suggested.
Keywords : coherent-synchronized dehydrogenation, piperidine, pyridine, determinant, mechanism, hydrogen peroxide, -radical
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