The reaction of monochloramide of benzene sulphonic acid with allyl chloride was studied. When using aprotic solvents chloro amidation reaction occurs, but with protic solvents ethylenechlorohydrin derivatives are formed.  Atoms of chlorine in synthesized N-β-chlorosulphamides are very reactive and are easily substituted with nucleophiles even with 10 % of alkali water. When losing atom of chlorine they transform to aziridinesulphamides.