NMR STUDY OF THE OXIDATIVE CHLOROPHOSPHORYLATION OF STYRENE–BUTADIENE RUBBER

N.A.Efendiyeva, A.M.Maharramov, A.A.Azizov, A.Y.Melikova, I.A.Bunyad-zadeh, R.M.Alosmanov

The reaction of oxidative chlorophosphorylation of styrene-butadiene rubber was studied by ¹H, ¹³C, and ³¹P NMR method. Investigations of functionalized styrene–butadiene rubber were carried out using low phosphorus containing samples selected from reaction medium at regular intervals. The obtained results have been discussed in detail, and make it possible to interpret the mechanism of the reaction and the structure of the polymer obtained

https://doi.org/10.32737/0005-2531-2019-3-20-24

Keywords : oxidative chlorophosphorylation, styrene-butadiene rubber, NMR measurements

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