PHASE EQUILIBRIA IN THE PbLa2S4–PbBi2S4 SYSTEM

O.M.Aliyev, D.S.Ajdarova, V.M.Ragimova, R.M.Agayeva

There have been studied phase equilibria and constructed T–x projection of PbLa₂S₄–PbBi₂S₄ system state diagram. Creation of quater sulfide PbLaBiS₄ melting congruently at 1025 K has been establihed. Compound PbLaBiS₄ has been crystallized in the orthorhombic syngony with parameters of elementary cell: a=1.170, b=1.451, c=0.412 nm s.g. Pnam, z=4

Keywords : diagram of state, compound, sulfosalts, monocrystals, peritectic

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