MECHANISM OF BIOMIMETIC OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE BY HYDROGEN PEROXIDE
The process of gas-phase oxidation of cyclohexane was studied in the presence of a heterogeneous biomimetic catalyst (per-FTPhPFe(III)OH/Al2O3), at 130–2500C, in which high yields of cyclohexanone and cyclohexanol were obtained up to 25.2% with a selectivity of ~80% at a cyclohexane conversion of 34%. The mechanism of the conversion of cyclohexane to cyclohexanone has been studied in detail, and the coherently synchronized character of the reaction proceeding is shown
doi.org/10.32737/0005-2531-2021-1-61-66
Keywords : cyclohexane, oxidation, biomimetic catalysts, cyclohexanone, hydrogen peroxide
View article
SUBMITION
THE LAST NUMBER OF THE JOURNAL
№2 2026CONTENT
- EFFECT OF DEPOSITION CONDITIONS ON THE COMPOSITION OF CdS THIN FILMS FROM A NON-AQUEOUS ETHYLENE GLYCOL ELECTROLYTE- KINETICS AND MECHANISM OF THE PARTIAL OXIDATION OF PROPANE TO LOW-MOLECULAR CARBONYL COMPOUNDS ON A MODIFIED ZEOLITE CATALYSTMore
.png)