PHYSICO-CHEMICAL INTERACTION OF THE COPPER AND ANTIMONY IODIDES
The character of the mutual interaction of the components in the CuI-SbI3 system was studied by differential thermal analysis and X-ray phase analysis methods and its phase diagram was constructed. It was found that the system is quasi-binary and forms a monotectic phase diagram. The immiscibility region covers ~15-93 mol% SbI3 concentration interval at the monotectic equilibrium temperature (~ 4930С). The temperatures of polymorphic transformations of the CuI compound in the system drop slightly and these phase transitions take place by metatectic reactions
doi.org/10.32737/0005-2531-2021-1-43-47
Keywords : CuI-SbI3 system, fast-ion conductor, phase diagram, differential-thermal analysis, X-ray phase analysis
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