CATALYTIC TRANSFORMATION OF LIQUID-PHASE OXIDATION PRODUCTS OF 1-METHYLCYCLOPENTENE TO APPROPRIATE DIENE HYDROCARBONS

F.M. Mamedov, S.A.Alieva, Z.A.Ehtibarova, M.I.Nadiri, E.S.Mamedova

The transformation reaction of oxy compound of 1-methylcyclopentene, obtained by liquid- phase oxidation of appropriate cyclene over a catalyst Ba₃(PO₄)₂, with the volume velocity of supplying of raw materials, at temperature range of 100–395⁰C was studied. It has been established that the main products of reaction at temperature 360–380⁰C are methylcyclopentadienes-1,3 with an admixture of 2-methylcyclopentanone. At 100% conversion the obtained catalysate mainly consists of methylcyclopentadienes-1,3 with conjugated double bonds

Keywords : 1-methylcyclopentene, oxidate, methylcyclopentanoles, catalyst Ba3(PO4)2, methylcyclopentadienes

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