ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
CATALYTIC HYDROSILYLATION OF 5-METHYLHEXENE-5-YN-2-OL-1
A.M.Garamanov, N.Kh.Gusiev, D.G.Abdullaev, O.B.Abdiev, M.Sh.Gurbanov, S.A.Rzaeva

The addition of trialkylsilanes to 5-methylhexene-5-yn-2-ol-1 in the presence of H2PtCl6.6H2O proceeds via a triple bond, but with an advantageous yield (80-90%) of the β-isomer (relatively oxygen atom). The reaction of organosilicon 1,4-diene alcohol with 1-chloro-2,3-epoxypropane, boric acid and acrylonitrile produced corresponding chlorohydrin, tris-borate and nitrile

https://doi.org/10.32737/0005-2531-2019-2-62-66 

 

Keywords : 5-methylhexene-5-yn-2-ol-1, trialkylsilane, benzene, hydrosilylation, 1-chloro-2,3-epoxy­pro­pane, boric acid, acrylonitrile
View article