SUPRAMOLECULAR METALCOMPLEX CATALYTIC SYSTEMS ON THE BASE OF OIL PORPHYRINS FOR ALKENES OXIDATION
The cobalt- porphyrin complex modified by oligomer crown compounds has been obtained on the basis of oil-metalporphyrin concentrate. Synthesized complex possesses supramolecular catalytic properties. It is found that the resulting catalyst system is effective in the oxidation of alkenes and unsaturated organic compounds.
Keywords : porphyrin complex, crown compounds, clathrate metal complex, oxygenation of alkenes
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- SURFACES OF CRYSTALLIZATION AND PHASE RELATIONS IN THE 6Ag2Se+Ag8SiTe6«6Ag2Te+Ag8SiSe6 RECIPROCAL SYSTEM- ACID-BASE PROPERTIES OF PHOSPHORYLATED CRUMB RUBBERMore