LIQUID-PHAZE OXIDATION OF ALIPHATIC HYDROCARBONS IN A PRESENCE OF METAL-POLYMER COMPLEXES

R.H. Suleymanova, N.A.Zeynalov, O.T.Badalova, L.N.Qulubayova, N.F.Sharifzade, A.R.Quliyeva

The liquid-phaze oxidation of aliphatic hydrocarbons and their mixtures have been investigated in the condition of variable-valence metals complexes with polyethylene-polyamine. It is shown that the reaction is even more selective for a formation of hydroperoxide in investigated condition. The course of the oxidation reaction and its character depends on properties of metals which are “embedded” in the polymer matrix.

Keywords : oxygen, aliphatic hydrocarbons, n-dekan, n-dodekan, polyethylene-polyamine complexes, liquid-phaze

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