THE HYDROSILYLATION OF 3-(HEXEN-5-IN-2-ILOXY) PROPIONITRILE
A.M.Garamanov, M.Sh.Gurbanov, D.G.Abdullaev, N.Kh.Husiev, S.N.Allakhverdieva
The addition reaction of triorganosilanes to 3-(hexen-5-in-2-iloxy) propionitryle in the presence of acetylacetonate dicarbonyl rhodium catalyst proceeds on triple bonds in two directions obtaining of β(52–65%)- and γ(35–48%)-isomers mixture (relatively oxygen atom) and with advantage of β-yield.
Keywords : 3-(hexen-5-in-2-iloxy) propionitrile, triorganosilanes, acetylacetonate dicarbonyl rhodium, hydrosilylation, β-isomer, γ-isomer
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