ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
THE HYDROSILYLATION OF 3-(HEXEN-5-IN-2-ILOXY) PROPIONITRILE
A.M.Garamanov, M.Sh.Gurbanov, D.G.Abdullaev, N.Kh.Husiev, S.N.Allakhverdieva

 

The addition reaction of triorganosilanes to 3-(hexen-5-in-2-iloxy) propionitryle in the presence of acetylacetonate dicarbonyl rhodium catalyst proceeds on triple bonds in two directions obtaining of β(52–65%)- and  γ(35–48%)-isomers mixture (relatively oxygen atom) and with advantage of β-yield.

 

Keywords : 3-(hexen-5-in-2-iloxy) propionitrile, triorganosilanes, acetylacetonate dicarbonyl rhodium, hydrosilylation, β-isomer, γ-isomer
View article
SUBMITION
THE LAST NUMBER OF THE JOURNAL
No 1 2020
CONTENT
- CONTROL OF PROPANE PYROLYSIS PROCESS IN NONSTATIONARY CONDITIONSA.M.Aliyev, A.R.Safarov, I.V.Balayev, I.I.Osmanova, A.M.Guseynova
- CONVERSION OF METHANOL TO HYDROCARBONS ON BIMETALLIC CATALYSTS ON THE BASIS OF ZSM-5Т.А.BabaevaMore