ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
SYNTHESIS OF C11-C14 CYCLOOLEFINES OF FRAME STRUCTURE WITH PARTICIPATION OF H-FORMS OF NATURAL AND SYNTHETIC MORDENITE
H.M.Alimardanov, O.A.Sadigov, A.A.Jalilova, M.B.Almardanova

 

An efficient method of obtaining the C11–C14 cycloolefinic hydrocarbons of framing structure by codimerization of C5–C6-cyclodienes, of their methyl- and vinyl derivates under conditions of monomerization of dicyclopentadiene (DCPD) with participation of the H-forms of zeolite catalysts and the hydrogenation of the dienes synthesized in a flow system under atmospheric pressure has been developed. The use of zeolites as catalysts accelerates monomerization of dimer, reduces the rate of oligomerization of the forming cyclopentadiene and improves the reaction selectivity by its codimers with C6–C9 unsaturated cyclic hydrocarbons.

 

Keywords : dicyclopentadiene, cyclohexadiene-1,3, 4-vinylcyclohexene, bicyclo[2.2.1]hept-2-ene, H-forms of mordenite and zeolite NaY, dimerization, hydrogenation
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SUBMITION
THE LAST NUMBER OF THE JOURNAL
No 1 2020
CONTENT
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