ISSN 0005-2531 (Print) ISSN 2522-1841 (Online)
COPPER-CONTAINING NANOCOMPOSITES ON THE BASIS OF ISOTACTIC POLYPROPYLENE AND BUTADIENE-NITRILE RUBBER
T.M.Gulieva

The influence of additives of nanofillers containing nanoparticles of copper oxides stabilized by a polymer matrix of maleinized high-pressure polyethylene obtained by the mechano-chemical method on the structure and properties features of metal-containing nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber by x-ray phase and differential thermal analyses is studied. The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, that is probably due to the synergistic effect of interaction of copper-containing nanoparticles with maleic groups of maleinated high-pressure polyethylene. It is shown that nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber can be processed both by pressing method and by injection molding and extrusion methods. The prospects of using a nanofiller containing NPs of copper oxide stabilized by a high-pressure polyethylene matrix obtained by the mechanochemical method as an additive to TPE based on PP/BNR is shown to contribute to the creation of a fine-crystalline structure of the composition, and therefore its properties are improved and thereby expand scope of the obtained nanocomposite

doi.org/10.32737/0005-2531-2021-3-38-43 

Keywords : isotactic polypropylene, butadiene-nitrile rubber, metal-containing nanocomposites, copper oxide nanoparticles, maleinized high-pressure polyethylene, thermal properties; XRD, SEM analyses
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THE LAST NUMBER OF THE JOURNAL
№1 2024
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