THE EFFECTS OF PARAMETERS OF PROCESS ON THE VALUE OF DETERMINANTS IN THE COHERENT- SYNCHRONIZED REACTION DEALKODİMERİZATION OF 2-PİCOLİNE BY HYDROGEN PEROXIDE
The values for each experimental determinants have been calculated. The effect of the process parameters on the value of determinants in the coherent-synchronized reaction of dealcodimerization of 2-picoline by hydrogen peroxide has been studied. Based on these values a quantitative assessment of the impact of the primary reaction (decomposition of hydrogen peroxide) on the secondary (dealcodimerization of 2-picoline) is given. Proposed the most probable mechanism of the coherent-synchronized reactions of hydrogen peroxide decomposition and dealkodimerization of 2-picoline trough a free-radical chain mechanism, in which a key role in the oxidation of the substrate is played by-radikal
Keywords : coherent-synchronized, dealcodimerization of 2-picoline, hydrogen peroxide, determinant
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- ELECTROCHEMICAL BEHAVIOR OF BISMUTH IONS IN CITRATE SOLUTIONS- GAS-PHASE OXIDATION OF 2-PICOLINE BY “GREEN OXIDIZERS” H2O2 AND N2OMore