PHYSICO-CHEMICAL INTERACTION IN THE SbTeI−Bi2Te3 SYSTEM
The SbTeI−Bi2Te3 polythermal section of the phase diagram of the Sb2Te3+2BiI3↔Bi2Te3+2SbI3 reciprocal system was constructed using DTA and XRD methods. It was established that Bi2-xSbxTe3 solid solutions (α-phase) primarily crystallize from the liquid phase along this section. Subsequently, crystallization proceeds by a number of non- and monovariant reactions, α+γ1, α+γ2, and α+γ1+γ2 (γ1 and γ2 are solid solutions based on SbTeI, and BiTeI) heterogeneous regions of are formed in subsolidus
doi.org/10.32737/0005-2531-2020-3-46-49
Keywords : SbTeI−Bi2Te3 system, phase diagram, solid solutions, topological insulators, Rashba semiconductors
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